Strep-Tactin XT–modified sensor chips (ST)
XanTec’s Strep-Tactin XT–modified (ST) sensor chips are coated with a bioinert (poly)carboxylate matrix pre-functionalized with a recombinant 52 kDa Strep-Tactin XT tetramer. Although a member of the avidin family, Strep-Tactin XT exhibits only weak micromolar affinity for biotin and is therefore not suitable for stable immobilization of biotinylated biomolecules. Instead, it binds the 3 kDa Twin-Strep-Tag (TST) sequence with exceptionally high picomolar affinity, displaying typical dissociation rates (koff) of ≤ 10−5 s−11,2.
This enables defined, site-directed immobilization of TST fusion proteins under physiological conditions, ensuring uniform ligand orientation and preservation of biological activity. The Strep-Tactin XT/TST complex can be quantitatively regenerated using brief pulses of 3 M guanidine·HCl, with ST chips tolerating more than 100 regeneration cycles.
Compared with NTA/His-tag systems, ST chips exhibit markedly lower nonspecific binding of proteins and peptides, making them particularly suitable for kinetic and affinity studies involving these analytes.
XanTec offers three versions of Strep-Tactin XT–modified chips. The 2D STP chip provides superior diffusion properties, ideal for bulky analytes or weak binders with rapid kinetics. The STD200L and STHC200M chips enable higher immobilization densities for applications involving smaller analytes.
Key features:
- Fast assay development: No preconcentration or chemical activation required; ligand capture occurs under physiological conditions.
- Exceptional stability: Picomolar TST binding ensures virtually drift-free immobilization.
- Simple regeneration: Quantitative regeneration allows > 100 capture/regeneration cycles.
- Oriented immobilization: Uniform ligand orientation maximizes biological activity.
- Versatile capture capacity: Available on CMDP, CMD200L, and HC200M base coatings.
| Product code | STP | STD200L | STHC200M |
|---|---|---|---|
| Base coating | 2D, ultra-short CM-dextran (high density) | 3D, 200 nm bioinert CM-dextran (low density) | 3D, 200 nm bioinert polycarboxylate (medium density) |
| Capture immobilization capacity [µRIU]4 | ≈ 500–1,000 | ≈ 5,000–7,000 | ≈ 5,000–7,000 |
| Recommended ligands | TST-modified proteins and peptides | ||
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1 Apparent dissociation rate constants (koff) determined at ligand capture densities < 50% of maximum immobilization level.
2 Binding of Strep-Tag II is feasible but exhibits limited stability (koff ≈ 10−2–10−3 s−1).
3 All illustrations are schematic representations and are not drawn to scale; dimensions, densities, and spatial relationships do not reflect actual physical or chemical proportions.
4 Based on specific capture immobilization of 500 nM TST-GFP in PBS.